2.0 UV Treatment Technology Description

How it works

Ultraviolet radiation (UV) is light energy between 100 and 400nm wavelength, between the X-ray portion of the spectrum and the visible portion (Figure 2-1). In most UV disinfection applications, the short wave portion of the UV spectrum is used. This section is referred to as UV-C and spans from 200-280nm. In general, UV radiation of microorganisms causes chemical bonds to form in cellular DNA. The exposure thus interrupts normal DNA replication and organisms are killed or rendered inactive. UV disinfection of water is currently used in the drinking water, wastewater, and aquaculture industries. The development of UV technology for use in these industries has defined the operational parameters that influence the effectiveness of UV in water disinfection systems.

Figure 2-1

Problem of suspended sediment. Water clarity (transmissivity), exposure period, and radiation energy are the three factors that affect the performance of a UV disinfection plant. These three factors must be balanced to treat large volumes of water quickly, safely, and economically. In a shipboard application, removing suspended sediment and other particulates via primary filtration treatment is the most significant way to increase treatment effectiveness. Filtration allows exposure periods and energy consumption to be decreased, and flow rates increased. Optimal treatment effectiveness is achieved when the transmissivity of the water approaches 100 percent. While filtration of suspended matter (achieved by reverse osmosis or related technology) is obviously impracticable and uneconomical for ballast treatment, shipboard UV treatment is significantly improved with fine scale filtration (e.g., <100m ).

Treatment apparatus. UV ballast water treatment, like other water disinfection processes require that the water flow through a treatment "chamber" where it is "dosed" to disinfect it of the target microorganisms. The treatment chamber must be installed in the ballast water supply pipe between the primary filtration system (if available) and the ballast tanks of the vessel. Additional space may also be required in order to support the control and power modules that are associated with the different technologies. Tables 2-1 and 2-2 summarize technical specification for 1,200-gpm and 8,000-gpm treatment plants, respectively.

Treatment Performance

UV radiation as a disinfecting technique has been proven in multiple industrial applications, including drinking water disinfection and wastewater treatment. The effectiveness of this technology is directly related to the amount of UV radiation received by the target organisms. In considering UV treatment in ballast water systems, several factors must be addressed.

 

Table 2-1. Ultraviolet Secondary Treatment Equipment
General Operating Specifications for 1,200 GPM Systems

 Equipment Weight

Subunit Dimensions

  • Treatment Chamber
  • Power Module
  • Control Module
450 to 1,100 lbs (200 to 500 kg)

Example dimensions (height/length/width) from Aquionics, Inc. (1998) for treatment at 1,258 – 2,183 GPM:
25.6 ´ 19.7 ´ 30.1 inches (65 ´ 50 ´ 76.5 cm)
27.6 ´ 13.4 ´ 27.6 inches (70 ´ 34 ´ 70 cm)
27.6 ´ 58.3 ´ 27.6 inches (70 ´ 21 ´ 70 cm)

Energy Requirements
  • 3-25KW/hr
  • Power consumption depends on pretreatment filtration and target organism
Connections/Fittings/ Equipment/Room Environment
  • Intake diameters: 2 – 30 inches (5 – 76 cm)
  • Intake pressure: 40-70 PSI
  • Temperature is not a limit for this technology
 Operation Concerns
  • Maintenance
  • Environmental
  • Safety
 $ 2,200 – 4,000 per year (1,200 GPM system; assuming 10% duty cycle, one set backup lamps, and normal maintenance procedures)
  • Lamp life: 5,000-8,000 hrs, or 1 year
  • Lamp cleaning requirements vary by system design; some lamp fixtures are placed above the water.
  • Approx. 20-hrs labor maintenance required every third month if equipment is used continuously.
  • In the Pulsed UV technology, flash tubes don’t show any decrease of power when used for 100 to 150 million flashes (equiv. To approx. 1000-1500 hrs continuous use), actual tube life depends on usage; manufacturer doesn’t know when power decrease starts, but suggest replacement when power is 95% of original
  • Possible mercury discharge from mercury containing lamps, if broken.
  • Use of high voltage (440V) electricity. Possible exposure of crew to mercury if mercury containing lamps are broken.
  • Possibility of genetic mutation of organisms surviving treatment
Filtration Effects
  • Biological
  • Operational
 
  • Pretreatment filtration removes larger organisms and particles, which increases water transmittance and treatment effectiveness.
  • Pretreatment filtration also reduces power requirements and maintenance costs.
 Performance Issues
  • In general, corrosion is not a problem; equipment made of corrosion-resistant materials.
  • The presence of iron will cause the formation of a film at the water/UV interface. The more intense the system, the faster the formation.
  • Some equipment must have continuous water flow, or be turned off
Equipment Capital Purchase Cost
  • $ 10,200 – 102,000
  • excludes installation, price on per-unit basis

 Table 2-2. Ultraviolet Secondary Treatment Equipment
General Operating Specifications for 8,000 GPM Systems

Equipment Weight

Subunit Dimensions

  • Treatment Chamber
  • Power Module
  • Control Module
470 to 5,600 lbs (200 to 2600 kg)

Example dimensions (height/length/width) from Aquionics, Inc. (1998) for treatment at 4729 – 11,712 GPM:
43.3 ´ 55.2 ´ 46 inches (110 ´ 140 ´ 117 cm)
78.7 ´ 31.5 ´ 31.5 inches (200 ´ 80 ´ 80 cm)
78.7 ´ 19.7 ´ 31.5 inches (200 ´ 50 ´ 80 cm)

Energy Requirements
  • 12-125 KW/hr
  • Power consumption depends on pretreatment filtration and target organism
Connections/Fittings/ Equipment/

Room Environment

  • Intake diameters: 8 – 30 inches (20 - 76 cm)
  • Intake pressure: 40-145 PSI
  • Temperature is not a limit for this technology
Operation Concerns
  • Maintenance
  • Environmental
  • Safety
 
  • $ 2,200 – 4,000 per year (1,200 GPM system; assuming 10% duty cycle, one set backup lamps, and normal maintenance procedures)
  • Lamp life: 5,000-8,000 hrs, or 1 year
  • Lamp cleaning requirements vary by system design; some lamp fixtures are placed above the water.
  • Approx. 20-hrs labor maintenance required every third month if equipment is used continuously.
  • In the Pulsed UV technology, flash tubes don’t show any decrease of power when used for 100 to 150 million flashes (equiv. To approx. 1000-1500 hrs continuous use), actual tube life depends on usage; manufacturer doesn’t know when power decrease starts, but suggest replacement when power is 95% of original
  • Possible mercury discharge from mercury containing lamps, if broken.
  • Use of high voltage (440V) electricity. Possible exposure of crew to mercury if mercury containing lamps are broken.
  • Possibility of genetic mutation of organisms surviving treatment
 Filtration Effects
  • Biological
  • Operational
 
  • Pretreatment filtration removes larger organisms and particles, which increase water transmittance and treatment effectiveness.
  • Pretreatment filtration also reduces power requirements and maintenance costs
 Performance Issues
  • In general, corrosion is not a problem; equipment made of corrosion-resistant materials.
  • The presence of iron will cause the formation of a film at the water/UV interface. The more intense the system, the faster the formation.
  • Some equipment must have continuous water flow, or be turned off
Equipment Capital Purchase Cost
  •  $ 25,000 – 545,000
  • excludes installation, price on per-unit basis

 

Water clarity and the depth of UV transmittance through water in the treatment chamber are inversely related. Clearer water (low concentration of suspended sediments) allows for deeper UV transmittance; more turbid water (higher concentrations of suspended sediments) decreases UV transmittance. Suspended sediment absorbs and deflects UV energy, thereby decreasing the effectiveness of the treatment process to kill microorganisms. To compensate for turbidity, most treatment plants have an "auto feedback system" that continually adjusts the UV radiation (i.e., power) to keep the system operating at a predetermined treatment level. In the Innovatech’s treatment plant (refer to Figure 2-3), a sensor is attached to the outermost radius of the cylindrical treatment chamber. The sensor transmits data to the control circuitry of the treatment plant, and power sent to the UV bulbs is increased or decreased as necessary. This feedback system ensures that a predetermined amount of radiation is reaching the furthermost point in the treatment chamber. Dr. Robert LaFrenz of Innovatech (pers. comm., June 1998) stated that in their 8-12 inch diameter treatment chamber there is a 40-50% reduction in the UV energy transmitted to the outermost radius when treating water that is visibly lacking clarity, green in color, and has a measured transmissivity of about 7 nephelometric turbidity units (NTU’s). Dr. LaFrenz also reports that with 7NTU water, they estimate a 20% reduction in UV radiation throughout the treatment chamber (compared to 40-50% at the outermost point).

Other researchers report that the presence of iron in the treatment water also will reduce UV treatment efficacy by absorbing UV radiation and forming a precipitate film on the light/water interface. Radiation intensity has a direct effect on precipitate film formation. With high-energy systems, iron precipitate forms more rapidly then in low energy systems. At the present time, the chemical characterization of the precipitate formation process is not completely understood, although ongoing research is presently being conducted (Coogan, 1998).

The effectiveness of UV radiation treatment is measured by determining the amount of energy required to achieve a specified reduction in target populations. Table 2-3 provides the range of energy inputs required to achieve 90-99% population reductions in a variety of organisms. In the continuous-wave UV data in Table 2-3, to go from 90% (1log) to 99% (2log) killing effectiveness, a 50-200% power increase is needed.

 

Table 2-3. Energy Requirements for
UV Treatment Systems on Selected Organisms

 

Organism

Continuous UV
90% (1log) a Effectiveness
(mW-s/cm2)

Continuous UV
99% (2log) b Effectiveness
(mW-s/cm2)

Pulsed UV
90% (1log) c Effectiveness
(mW-s/cm2)

Cryptosporidium1

110

330

>16

Escherichia coli1

3-6

7-16

>13

Staphylococcus aureus1

2-5

7

>10

Vibrio cholerae2

6-7

7-13

NA

Infectious hepatitis2

5-8

8-15

NA

Poliovirus2

3-12

6-13

NA

Nematode eggs3

31-51

92

NA

Chlorella vulgaris4

12-14

22

NA

Blue-green algae4

300-600

NA

NA

Infectious pancreatic necrosis5

40

60

NA

1 Bacteria
2 Viruses
3 Protozoan
4 Algae
5 Fish Related Disease
a Aquionics, Inc., and Safe Water Solutions Inc.
b Aquafine Corporation and Safe Water Solutions Inc.
c Innovatech Inc.

 

BalsurvUVFig2.jpg (38503 bytes)

Current UV radiation technology is dominated by two delivery techniques: continuous-wave and pulsed-wave delivery. The continuous wave delivery systems provide lower level constant flow UV radiation into the water treatment chamber. Continuous-wave techniques are further segregated into low and high intensity treatments. The difference in these treatment techniques is the intensity of the UV radiation that is provided by the lamps. UV lamp performance is designed to pressure and intensity specifications. The internal operating pressure and UV intensity irradiated by the lamp will define the effectiveness of the system design. Therefore, it is necessary that these systems be engineered to the desired disinfection goals of the system.

The pulsed-wave UV delivery system provides radiation doses through a flashing of the source lamp. The effect of this pulsing technique is to provide short ‘bursts’ of higher energy into the system. The speed of the pulsing and the intensity of the UV radiation are specific to the design of the system and the available power supply (refer to Figure 2-3).

The use of high intensity UV, pulsed or continuous wave delivery, will increase the range of transmittance, and allow for more effective treatment of higher turbidity water or larger volumes of low turbidity water. High intensity UV systems also have proportionately higher energy demands, which must be considered during design and installation of shipboard systems.

Biological Considerations

Research conducted in the field of UV radiation treatment focuses on the treatment of human and aquatic pathogens. The most intense research has been done for the aquaculture and water treatment industries (drinking and disposal). The target organisms for these industries are usually concerned with bacterial and viral infections of either human or fish populations. The target organisms for the treatment of ballast water include the same bacterial and viral components, but also the larval stages of many estuarine or marine organisms and live organisms such as fish, crabs, worms, and algae.

Oemcke and vanLeeuwen (1998) suggests that zooplankton are unlikely to be significantly affected by UV radiation. Their research presents the variability of UV radiation required to inflict significant reductions on organism populations. To achieve a 1log (90%) removal of Amphidinium sp. a dinoflagellate alga, in 30 minutes required 130,000F Ws/cm2 and a 2log (99%) reduction were estimated to require 350,000F Ws/cm2. With UV radiation below these levels effective population reductions occurred after three to five days of treatment.

Figures 2-3 A, B, and C

BalsurvUVFig3.jpg (111893 bytes)

 

Filtration Effects

The use of filtration at more that one level may need to be considered in order to achieve the removal of larger animals and the removal of sediment and larval stage organisms. As previously discussed, the ability of UV radiation to treat unfiltered water is highly dependent of water clarity/turbidity. Most estuarine waters contain significant organic and inorganic suspended particles, which will reduce the transmissivity of the water and the effectiveness of UV treatment. To achieve kill ratios equivalent to treatment plants receiving filtered water, UV equipment receiving unfiltered water must increase energy and/or exposure period to achieve treatment criteria (i.e., radiation at a preset level at all points in the treatment chamber).

Based on data and interview information provided by several vendors, water that is filtered to a range of 25-50F m is optimal for removing particulate interferences and organisms larger than bacteria and viruses. Filtering intake water to 25-50F m also excludes target organisms such as zebra mussel veligers and toxic dinoflagellate cysts. The majority of the vendors responding to Battelle’s survey grouped their responses for 100F m, 250F m, and unfiltered water together, indicating similar biological effectiveness occur across these higher filtration levels.

Robustness of UV Radiation Systems

BalsurvUVFig4.jpg (30688 bytes)The construction of the majority of the UV radiation treatment chambers is of 316 stainless steel. This material is resistant to the corrosive effects of seawater, and stress conditions typical of shipboard conditions. Some of the UV chambers are constructed of 316 stainless steel and PVC. The irradiation chambers are constructed with the lamps enclosed in a high strength and clarity quartz lamp. The quartz sleeve serves to protect the lamp from direct contact with the water and as a filtering mechanism allowing only targeted wavelengths to pass through.

The power and control modules associated with the UV chamber consists of high and low voltage power units with microchips that control the majority of the units’ functions. The units are enclosed in steel cabinets that provide protection from physical damage. According to several of the vendors, the power module does not need to be located adjacent to the UV chambers; however the electrical resistance over the distance traveled for the electricity would need to investigated on an individual basis. The control units are generally lower voltage than the power modules and contain the majority of the computerized control modules. These may be located at further distances from the UV chamber and generally require more protection from fluctuations in heat, humidity, water, and physical damage.

Ease of Operation

The UV radiation systems that were investigated during the study appeared to be relatively easy to operate. As described in Section 2.2, most UV systems are composed of three separate machines in sequence that produce the desired outcome of UV radiation. The control modules themselves are microchip based and will require some input from trained personal; this may be as simple as learning to input on and off sequences. The power modules are self-contained units that will require little attention when functioning. The UV chambers are also self-contained and require little attention.

Maintenance procedures will need to be acquired by some members of the crew. Maintenance procedures include

  • Cleaning the quartz sleeves
  • Changing of lamps,
  • Ensuring proper power module function
  • Overall system upkeep

An estimate of man-hours required for operation and maintenance of onboard UV systems could not be made from the data collected from this survey. Although, it appears that each vessel and system will vary depending on design, it appears that the complexity of operating a UV treatment plant is similarly to other shipboard systems. Whether specific ships have available man-hours to maintain the equipment is undetermined. Many commercial vessels operate with minimum crews, and the additional responsibility to maintain a UV plant may require that ship operators add crew, and thereby add significant costs to their business operations.

Safety

There are several UV system-specific safety concerns that should be addressed relative to shipboard application of this technology. The first issue is the use of high voltage electricity (220/440 V) to power the system. Considering that other shipboard machinery runs on high voltage electricity this should not be a major factor assuming that shipboard safety requirements for high voltage electricity will to be adhered to during the installation process. The operation of the UV radiation systems should raise no additional concerns if the system is installed and maintained properly. If the system is improperly installed or poorly maintained, there is risk of electrical accident comparable to other shipboard systems.

The second issue is the use of mercury-containing lamps to generate the UV radiation. The lamps’ source of the UV radiation may come from several sources including zeon (inert gas) or mercury. The systems that use mercury containing lamps (~ 20mg/lamp) keep them protected within the treatment chamber by the use of a quartz sleeve. The use of mercury containing lamps could be a concern onboard a ship given the relatively high potential for physical damage during storage and installation.

The third potential safety issue is related to UV exposure to plastic pipework and fittings. If UV radiation is exposed to plastic pipework for prolonged periods (such as may occur during installation/operation of UV systems aboard a ship), the pipes could potentially degrade and fail. Risk of injury or operational failure of equipment will depend on the use and contents of the failed pipework. Any treatment system permanently installed on U.S.-flagged ships must meet all applicable U.S. Coast Guard regulations and insurance underwriters’ criteria.

Environmental Concerns

Mercury. The major environmental concern with UV treatment is accidental release of low-level mercury if mercury-containing lamps are broken or improperly disposed. Mercury is a well-known environmental toxicant, the release of which is regulated by numerous laws and agency programs.

Genetic mutation risk. Another environmental concern, which has postulated but not investigated by others (e.g., Lloyd’s Register, 1995), is genetic mutation. Aquatic microorganisms that survive the UV treatment process could be genetically mutated (by damage caused to their DNA from action of UV photons). It is expected that most or all of the surviving organisms with damaged genetic material will fail to procreate. However, a slim possibility exists that genetically altered DNA will benefit the surviving organisms, and that they will thrive in discharged environment. Although the risk of thriving mutants is considered remote, the possibility cannot be quantified until laboratory research is conducted using monocultures of test organisms exposed to UV radiation under a range of conditions.

In evaluating potential for genetic mutation among microorganisms that survive UV-treatment, one must weigh the low possibility of a mutation being passed to subsequent generations of the organism plus the low possibility that the mutation will give the organism a competitive advantage in the receiving ecosystem. Additionally, one must understand that shipboard ballast water treatment is unlike other biocide applications where there is significant risk of genetic mutation among surviving microorganisms. For example, in a biomedical laboratory setting, technicians apply chemical , radiation, and heat treatments to various instruments and containers. The materials are repeatedly treated and usually the treated materials remain in a confined area. Microbes that are able to resist the first treatment find that their competitors are dead, and they can now exploit the newly vacated habitat and available food to their maximum advantage (i.e., population growth). When the instruments and containers are then treated a second time, the resistant microbes comprise a much larger fraction of the population. For these reasons, most biomedical facilities and laboratories, use different biocides at different times to limit chances of developing resistant strains of microbes.

Unlike a biomedical facilities and laboratories, ballast water treatment is a 1-time event. Microorganisms that survive a treatment process, will not be treated a second time, and a vigorous resistant population does not have the chance to develop. Furthermore, surviving microorganisms discharged to the receiving environment when ballast is offloaded are injected into an environment where they must compete with the resident microorganisms. It is unlikely that any genetic mutations caused by the ballast water treatment process (or preexisting genetic conditions that allowed the microorganism to survive the treatment process) will provide the organism with competitive advantages in the receiving environment.

Operation and Maintenance (O&M) Costs

The cost of O&M procedures range from $2,200 to $11,000 per year, for 1,200GPM and 8,000GPM systems respectively (Tables 2-1 and 2-1). The O&M procedures associated with these systems are discussed under ease of operation section and will require some labor hours. The major costs of O&M, not including labor, will be for replacement lamps and spare parts for the generator and control units. A crucial O&M concern will be to simplify the procedures so that a minimally trained seaman may make repairs without harming the system or allowing for extended down time.

01 April 2001
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